Chemical Name |
Triethylborane |
Synonym |
(C2H5)3B TRIETHYLBORANE TRIETHYLBORANE SOLUTION, ~15% IN HEXANE TRIETHYLBORANE, 95+% Triethylborane Triethylborane, in tetrahydrofuran Triethylborane-1,3-diaminopropane complex Triethylborine Triethylboron borane,triethyl- triethyl borane triethyl-boran triethyl-borane triethylborane,teb,inhexanes {} {} {} {} {uni_hamburg} 三乙基硼 1M四氢匡威1970s水蜜桃色官方(中国)官方网站溶液 三乙基硼 溶液 乙基硼,三乙羟基硼 |
PubChem Substance ID |
87577677 |
Beilstein Registry Number |
1731462 |
EC Number |
202-620-9 |
Reaxys-RN |
1731462 |
Merck Number |
9668 |
Chemical Name Translation |
三乙基硼 |
Wiswesser Line Notation |
2B2&2 |
LabNetwork Molecule ID |
LN00164556 |
InChI |
InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3 |
MDL Number |
MFCD00009022 |
CAS Number |
97-94-9 |
GHS Symbol
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 700 ppm/4H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 22700 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 235 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New York, John Wiley & Sons, Inc., 1964 Volume(issue)/page/year: -,693,1964
WGK Germany |
1 |
Precautionary statements |
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P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
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P222
Do not allow contact with air. 不要与空气接触。
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P231+P232
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P240
Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
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P241+P242+P243
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P260
Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
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P270
Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
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P271
Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
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P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
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P301+P330+P331+P310
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P303+P361+P353
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P303+P361+P353+P310+P363
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P304+P340
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P304+P340+P310
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P305+P351+P338
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P305+P351+P338+P310
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P308+P311
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P370+P378
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P403+P233
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P405
Store locked up. 上锁保管。
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P422
Store contents under… 存储目录在…之下。
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P501
Dispose of contents/container to..… 处理内容物/容器.....
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Hazard statements |
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H314
Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
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H335
May cause respiratory irritation 可能导致呼吸道刺激
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H351
Suspected of causing cancer 怀疑致癌
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H261
In contact with water releases flammable gas 与水接触时释放可燃气体。
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H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
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H250
Catches fire spontaneously if exposed to air 暴露于空气自发着火
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H304
May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
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H336
May cause drowsiness or dizziness 肯能导致嗜睡或头晕
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H411
Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
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H361
Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
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H373
May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
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H301
Toxic if swallowed 吞食有毒
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Personal Protective Equipment |
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Signal word |
Danger |
RTECS |
ED2100000 |
Safety Statements |
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S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
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S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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S33
Take precautionary measures against static discharges 对静电采取预防措施;
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S36/37
Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
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S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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S43
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
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S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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S62
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
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S9
Keep container in a well-ventilated place 保持容器在通风良好的场所;
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Packing Group |
II |
UN Number |
2924 3399 |
Risk Statements |
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R11
Highly flammable 非常易燃
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R17
Spontaneously flammable in air 在空气中能够自燃
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R19
May form explosive peroxides 可能生成易爆的过匡威1970s水蜜桃色官方(中国)官方网站质
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R22
Harmful if swallowed 吞咽有害
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R34
Causes burns 会导致灼伤
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R37
Irritating to respiratory system 刺激呼吸道
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R48/20
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R51/53
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R62
Possible risk of impaired fertility 有削弱生殖能力的危险
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R65
Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
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R67
Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
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Storage condition |
充氩密封2-8°C保存 充氩保存 0-6°C Air Sensitive |
Hazard Codes |
4.3 F,C F,Xn,N F;C;N |
Hazard Class |
3/8 |
Warnings |
危化品目录(2015) |
Restrict |
危险品 |
Usually used as catalyst for Allylation of aldehydes,Decarboxylative C-C bond cleavage reactions,Regioselective hydroxyalkylation of unsaturated oxime ethers.And also used as reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes,synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential.
{uni_hamburg} Short: III/38A
{ALD} Merck: 14,9668
{ALF} Reacts with metal enolates to give the enoxytriethylborates, useful in selective alkylation and aldol reactions: Tetrahedron Lett., 2975 (1976); 32, 5521 (1991).
{uni_hamburg} Short: III/20a
{ALF} Radical initiator for hydrostannylation of alkynes: Tetrahedron, 45, 923 (1989).
{uni_hamburg} Short: III/35A
{ALD} Merck: 14,9668
Beilstein:4(4)4359