Chemical Name |
Bis(cyclopentadienyl)zirconium dichloride |
Synonym |
Bis(cyclopentadienyl)zirconium(IV) dichloride {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} |
EC Number |
215-066-8 |
Beilstein Registry Number |
2384789 |
PubChem Substance ID |
87577925 |
Chemical Name Translation |
二氯二茂锆 |
Wiswesser Line Notation |
L50J 0-ZR-GG- 0L50J |
LabNetwork Molecule ID |
LN01746727 |
MDL Number |
MFCD00003726 |
CAS Number |
1291-32-3 |
Canonical SMILES |
[][Zr](Cl)(Cl)[].c1cccc1.c2cccc2 |
GHS Symbol
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 30 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 333 ug/plate REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988
Signal word |
Danger |
WGK Germany |
3 |
Safety Statements |
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S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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S36
Wear suitable protective clothing 穿戴适当的防护服;
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S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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S37
Wear suitable gloves 戴适当手套;
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S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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S60
This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
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S9
Keep container in a well-ventilated place 保持容器在通风良好的场所;
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Risk Statements |
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R34
Causes burns 会导致灼伤
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R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Precautionary statements |
|
-
P234
Keep only in original container. 只保留在原来的容器中。
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P260
Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
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P270
Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
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P271
Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
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P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
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P301+P330+P331
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P303+P361+P353
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P303+P361+P353+P310+P363
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P305+P351+P338
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P310
Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
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P390
Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
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P405
Store locked up. 上锁保管。
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P501
Dispose of contents/container to..… 处理内容物/容器.....
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RTECS |
ZH7525000 |
Hazard statements |
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-
H315
Causes skin irritation 会刺激皮肤
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H319
Causes serious eye irritation 严重刺激眼睛
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H335
May cause respiratory irritation 可能导致呼吸道刺激
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H290
May be corrosive to metals 可能腐蚀金属。
|
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Packing Group |
III |
UN Number |
3261 |
Storage condition |
2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive Refrigerator (+4°C) {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored |
Hazard Codes |
8 Xi |
Hazard Class |
8 |
用于合成许多早期过渡金属络合物和妈妈的外遇二化合物
{uni_hamburg} Short: III/35D5
{ALF}
{uni_hamburg} Short: III/20b
{ALF} For reaction of alkene-zirconocene complexes with cyclic enol ethers, see: Angew. Chem. Int. Ed., 43, 3932 (2004).
{ALF} Versatile organometallic reagent and catalyst. For a brief review, see: Synlett, 375 (1999). Other reviews: Organozirconium compounds in organic synthesis: Synthesis, 1 (1988); Recent advances in the chemistry of zirconocene and related compounds: Tetrahedron, 51, 4255 (1995); Synthetic applications of zirconocene complexes: Tetrahedron, 52, 12853 (1996). Formation of carbon-carbon bonds via 'zirconocene' (obtained by reaction of the dichloride with Grignard or lithium reagents): Synlett, 299 (1995). Reduction with n-BuLi in the presence of 2-butyne leads to a zirconium metallocycle: Tetrahedron Lett., 27, 2829 (1986), which is a useful intermediate for the synthesis of phospholes and analogous heterocycles in which the Zr atom is replaced by As, Sb, Bi, Si, Ge, Sn, Ga, S, Se or B: Org. Synth. Coll., 9, 653 (1998), and references therein: