Chemical Name |
Tris(Pentafluorophenyl)Borane |
PubChem Substance ID |
87558752 |
Reaxys-RN |
2931347 |
Merck Number |
9755 |
Synonym |
Tris(perfluorophenyl)borane {LY} Tris(perfluorophenyl)borane {} {LY} Tris(perfluorophenyl)borane {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe |
Beilstein Registry Number |
2931347 |
EC Number |
250-023-7 |
Chemical Name Translation |
三(五氟苯基)硼烷 |
LabNetwork Molecule ID |
LN00145630 |
InChI |
InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25 |
MDL Number |
MFCD00269813 |
CAS Number |
1109-15-5 |
Canonical SMILES |
FC1=C(F)C(F)=C(F)C(F)=C1B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F |
GHS Symbol
WGK Germany |
3 |
Precautionary statements |
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P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
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P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
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P302+P352+P332+P313+P362+P364
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P305+P351+P338
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P305+P351+P338+P337+P313
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P362
Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
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Hazard statements |
|
-
H315
Causes skin irritation 会刺激皮肤
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H319
Causes serious eye irritation 严重刺激眼睛
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H335
May cause respiratory irritation 可能导致呼吸道刺激
|
Hazard Codes |
T Xi Xi,T,N,Xn,F |
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Signal word |
Warning |
Storage condition |
2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen <0°C <;0 Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} |
Safety Statements |
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S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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S36
Wear suitable protective clothing 穿戴适当的防护服;
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S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
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S37/39
Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
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S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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S60
This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
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S61
Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
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S62
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
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UN Number |
UN 1268 3/PG 2 UN2811 |
Risk Statements |
|
-
R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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Packing Group |
III |
Hazard Class |
6.1 |
A useful component of Ziegler-Nattametallocene catalyst for polyolefins.
{ALFA} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to ß-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethylsilane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002).
{ALF} Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between
{ALFA} Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002).
{SA} J. Am. Chem. Soc. 129 , 1880, (2007) 摘要
{SA} Merck 14 ,9755