Chemical Name |
3-Butenylmagnesium Bromide |
CAS Number |
7103-09-5 |
EC Number |
250-023-7 |
Beilstein Registry Number |
2384789 |
MDL Number |
MFCD00209554 |
PubChem Substance ID |
24866263 |
Synonym |
3-丁烯基溴化镁 3-丁烯溴化镁 3-丁烯基溴化镁 溶液 |
Chemical Name Translation |
3-丁烯基溴化镁 |
LabNetwork Molecule ID |
LN01314450 |
GHS Symbol
Signal word |
Danger |
WGK Germany |
3 |
Safety Statements |
|
-
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
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S36/37/39
Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
-
S45
In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
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S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
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S43
In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
-
S36/37
Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
|
Risk Statements |
|
-
R11
Highly flammable 非常易燃
-
R19
May form explosive peroxides 可能生成易爆的过免费播放质
-
R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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R14/15
Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
-
R40
Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
-
R34
Causes burns 会导致灼伤
|
Precautionary statements |
|
-
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
-
P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
-
P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
-
P305+P351+P338
-
P223
Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
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P422
Store contents under… 存储目录在…之下。
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P231+P232
-
P370+P378
-
P402+P404
-
P403+P235
|
Hazard statements |
|
-
H314
Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
-
H351
Suspected of causing cancer 怀疑致癌
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H260
In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
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H225
Highly flammable liquid and vapour 高度易燃液体和蒸气
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H335
May cause respiratory irritation 可能导致呼吸道刺激
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H302
Harmful if swallowed 吞食有害
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) |
Hazard Codes |
F,Xn 4.3 |
UN Number |
|
Storage condition |
密封充氩保存 |
Packing Group |
Ⅰ |
从L-酒石酸合成(–)-muricatacin中,3-丁烯溴化镁用于一种非对映体选择性的关键步骤,也用于钌免费播放催化下的成环反应。