Chemical Name |
3-Butyn-1-ol |
CAS Number |
927-74-2 |
Alfabeta Name |
BUTYNOL 31--- |
MDL Number |
MFCD00002955 |
PubChem Substance ID |
87563786 |
EC Number |
213-161-9 |
Beilstein Registry Number |
773710 |
Reaxys-RN |
773710 |
Synonym |
3-Butyn-1-ol {LY} 3-Butyn-1-ol {} {LY} 3-Butyn-1-ol {} {} {LY} 3-Butyn-1-ol {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Butyn-1 |
Chemical Name Translation |
3-丁炔-1-醇 |
InChIKey |
OTJZCIYGRUNXTP-UHFFFAOYSA-N |
Wiswesser Line Notation |
Q3UU1 |
LabNetwork Molecule ID |
LN00008189 |
Canonical SMILES |
C#CCCO |
GHS Symbol
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05171
Warnings |
IRRITANT, FLAMMABLE |
WGK Germany |
3 |
Hazard statements |
|
-
H226
Flammable liquid and vapour 易燃液体和蒸气
-
H315
Causes skin irritation 会刺激皮肤
-
H319
Causes serious eye irritation 严重刺激眼睛
-
H335
May cause respiratory irritation 可能导致呼吸道刺激
|
Personal Protective Equipment |
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
Hazard Codes |
3 |
RTECS |
ES0710000 |
Precautionary statements |
|
-
P210
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
-
P233
Keep container tightly closed. ?保持容器密闭。
-
P240
Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
-
P241+P242+P243
-
P261
Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
-
P264
Wash hands thoroughly after handling. 处理后要彻底洗净双手。
-
P280
Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
-
P302+P352+P332+P313+P362+P364
-
P305+P351+P338
-
P305+P351+P338+P337+P313
-
P332+P313
-
P362
Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
-
P370+P378
-
P403+P235
-
P501
Dispose of contents/container to..… 处理内容物/容器.....
|
Signal word |
Warning |
Safety Statements |
|
-
S16
Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
-
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
-
S36
Wear suitable protective clothing 穿戴适当的防护服;
-
S37/39
Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
|
Risk Statements |
|
-
R10
Flammable 易燃
-
R36/37/38
Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
|
UN Number |
1986 1987 |
Packing Group |
III |
Hazard Class |
3 |
Storage condition |
2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Flammables area RT, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, st |
{ALD} Beilstein:1(4)2219
{ALF} For examples of Sonogashira coupling with aryl iodides in the presence of trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, CuI and Et3N in acetonitrile, see: J. Med. Chem., 38, 1837 (1995).
{uni_hamburg} Short: II/14a
{uni_hamburg} Short: II/2
{ALF} The triflate ester cyclizes on prolonged reaction with Na trifluoroacetate in TFA to give cyclobutanone: Org. Synth. Coll., 6, 324 (1988).